Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size.
نویسندگان
چکیده
The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe(IV/III) redox potential.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 22 شماره
صفحات -
تاریخ انتشار 2013